Intercomparison of oxygenated volatile organic compound measurements at the SAPHIR atmosphere simulation chamber
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چکیده
منابع مشابه
Technical Note: Intercomparison of formaldehyde measurements at the atmosphere simulation chamber SAPHIR
The atmosphere simulation chamber SAPHIR at the Research Centre Jülich was used to test the suitability of state-of-the-art analytical instruments for the measurement of gas-phase formaldehyde (HCHO) in air. Five analyzers based on four different sensing principles were deployed: a differential optical absorption spectrometer (DOAS), cartridges for 2,4-dinitrophenylhydrazine (DNPH) derivatizati...
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The simulation chamber SAPHIR at Forschungszentrum Jülich has UV permeable teflon walls facilitating atmospheric photochemistry studies under the influence of natural sunlight. Because the internal radiation field is strongly affected by construction elements, we use external, radiometric measurements of spectral actinic flux and a model to calculate mean photolysis frequencies for the chamber ...
متن کاملA new plant chamber facility, PLUS, coupled to the atmosphere simulation chamber SAPHIR
A new PLant chamber Unit for Simulation (PLUS) for use with the atmosphere simulation chamber SAPHIR (Simulation of Atmospheric PHotochemistry In a large Reaction Chamber) has been built and characterized at the Forschungszentrum Jülich GmbH, Germany. The PLUS chamber is an environmentally controlled flow-through plant chamber. Inside PLUS the natural blend of biogenic emissions of trees is mix...
متن کاملUrban flux measurements reveal a large pool of oxygenated volatile organic compound emissions
Atmospheric chemistry is fueled by a large annual influx of nonmethane volatile organic compounds (NMVOC). These compounds influence ozone formation, lead to secondary organic aerosol production, and play a significant role for the oxidizing capacity of the atmosphere. The anthropogenic NMVOC budget is considerably uncertain due to the diversity of urban emission sources. Here, we present compr...
متن کاملCharacterisation of the photolytic HONO-source in the atmosphere simulation chamber SAPHIR
HONO formation has been proposed as an important OH radical source in simulation chambers for more than two decades. Besides the heterogeneous HONO formation by the dark reaction of NO2 and adsorbed water, a photolytic source has been proposed to explain the elevated reactivity in simulation chamber experiments. However, the mechanism of the photolytic process is not well understood so far. As ...
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ژورنال
عنوان ژورنال: Journal of Geophysical Research
سال: 2008
ISSN: 0148-0227
DOI: 10.1029/2008jd009865